How are LiFePO4 batteries safer than other lithium batteries?

Phosphate-based batteries offer superior chemical and mechanical structure that does not overheat to unsafe levels. Thus, providing an increase in safety over lithium-ion batteries made with other cathode materials. This is because the charged and uncharged states of LiFePO4 are physically similar and highly robust, which lets the ions remain stable during the oxygen flux that happens alongside charge cycles or possible malfunctions. Overall, the iron phosphate-oxide bond is stronger than the cobalt-oxide bond, so when the battery is overcharged or subject to physical damage then the phosphate-oxide bond remains structurally stable; whereas in other lithium chemistries the bonds begin breaking down and releasing excessive heat, which eventually leads to thermal Runaway. Lithium phosphate cells are incombustible, which is an important feature in the event of mishandling during charging or discharging. They can also withstand harsh conditions, be it freezing cold, scorching heat or rough terrain. When subjected to hazardous events, such as collision or short-circuiting, they won’t explode or catch fire, significantly reducing any chance of harm. If you’re selecting a lithium battery and anticipate use in hazardous or unstable environments, LiFePO4 is likely your best choice. It’s also worth mentioning, LiFePO4 batteries are non-toxic, non-contaminating and contain no rare earth metals, making them an environmentally conscious choice.

Safety in Battery Storage (blog)

In this Tech Video we cover the importance of battery safety and why LiFeP04 batteries offer excellent power in a more user-friendly package. LiFeP04 batteries are both safer and more environmentally friendly than their counterparts due to their superior chemistry.